Trifolin

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Trifolin
Trifolin structure
Names
IUPAC name
5,7-dihydroxy-2-(4-hydroxyphenyl)-3-[(2S,3R,4S,5R,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxychromen-4-one
Other names
Kaempferol 3-O-beta-D-galactoside
Kaempferol-3-O-galactoside
Identifiers
23627-87-4
ChEBI CHEBI:31742 YesY
ChemSpider 10306173
Jmol 3D model Interactive image
PubChem 5282149
  • InChI=1S/C21H20O11/c22-7-13-15(26)17(28)18(29)21(31-13)32-20-16(27)14-11(25)5-10(24)6-12(14)30-19(20)8-1-3-9(23)4-2-8/h1-6,13,15,17-18,21-26,28-29H,7H2/t13-,15+,17+,18-,21+/m1/s1
    Key: JPUKWEQWGBDDQB-DTGCRPNFSA-N
  • C1=CC(=CC=C1C2=C(C(=O)C3=C(C=C(C=C3O2)O)O)OC4C(C(C(C(O4)CO)O)O)O)O
Properties
C21H20O11
Molar mass 448.37 g/mol
Density 1.791 g/mL
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Trifolin is a chemical compound. It is the kaempferol 3-galactoside. It can be found in Camptotheca acuminata,[1] in Euphorbia condylocarpa[2] or in Consolida oliveriana.[3]

Kaempferol 3-O-galactosyltransferase is an enzyme that catalyzes the chemical reaction:
UDP-galactose + kaempferol → UDP + kaempferol 3-O-beta-D-galactoside (trifolin).[4] It can also be found in seedlings of Vigna mungo.[5]

References

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  5. Partial Purification and Some Properties of Flavonol 3-O-Glycosyltransferases from Seedlings of Vigna mungo, with Special Reference to the Formation of Kaempferol 3-O-Galactoside and 3-O-Glucoside. Nariyuki Ishikura and Masami Mato, Plant Cell Physiol, 1993, 34 (2), pages 329-335, (abstract)